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Complexation of palladium(II) and copper(II) halides with the stable 4-methyliminomethyl-2,2,5,5-tetramethyl-3-imidazoline-1-oxyl radical and the addition of alcohols

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Coordination compounds of palladium(II) and copper(II) halides with 4-methyliminomethyl-2,2,5,5-tetramethyl-3-imidazolin-1-oxyl have been synthesized.

  2. 2.

    When copper(II) halide reacts with 4-methyliminomethyl-2,2,5,5-tetramethyl-3-imidazolin-1-oxyl in anhydrous alcohols, a molecule of alcohol adds at the C=N bond of the aliphatic segment of the starting ligand. The coordination compounds that form by this reaction of the coordinated ligand were isolated.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

    S. V. Larionov, M. I. Avdeeva, V. I. Ovcharenko, I. A. Grigor'ev & L. B. Volodarskii

  2. Novosibirsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    S. V. Larionov, M. I. Avdeeva, V. I. Ovcharenko, I. A. Grigor'ev & L. B. Volodarskii

Authors
  1. S. V. Larionov
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  2. M. I. Avdeeva
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  3. V. I. Ovcharenko
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  4. I. A. Grigor'ev
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  5. L. B. Volodarskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2797–2802, December, 1983.

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Larionov, S.V., Avdeeva, M.I., Ovcharenko, V.I. et al. Complexation of palladium(II) and copper(II) halides with the stable 4-methyliminomethyl-2,2,5,5-tetramethyl-3-imidazoline-1-oxyl radical and the addition of alcohols. Russ Chem Bull 32, 2510–2514 (1983). https://doi.org/10.1007/BF00954483

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  • DOI: https://doi.org/10.1007/BF00954483

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