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Step-by-step telomerization of propylene and 1-hexene by carbon tetrabromide

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of CBr4 with propylene and 1-hexene can be carried out depending on the method of initiation, as an addition reaction with tne formation of CBr3CH2CHBrCH3 and CBr3CH2-CHBr(CH2)3Cu3 or as a step-by-step telomerization with the formation of CBr2(CH2CHBrCH3)2 and CBr2(CH2CHBrCH2CH2CH2CH3)2.

  2. 2.

    The addition of compounds containing a Cur3 group to unsaturated compounds proceeded by cleavage of tne C-Br bond during initiation by Fe(CO)5+DMFA.

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Literature cited

  1. N. S. Jharasch, E. V. Jansen, and W. H. Urry, J. Am. Chem. Soc.,68, 154 (1946).

    Google Scholar 

  2. T. Asahara and M. C. Chou, Bull Chem. Soc., Japan, 42 (1969).

  3. R. Kh. Freidlina, F. K. Velichko, and L. V. Vinogradova, Dokl. Akad. Nauk SSSR,222, 625 (1975).

    Google Scholar 

  4. R. Lantsch and E. Kysela, German Patent No. 2655007 (1978); Chem. Abstr.,89, 146409 (1978).

    Google Scholar 

  5. G. Rabilloud, Bull. Soc. Chim. France, 2149 (1965); Chem. Abstr.,63, 13014e (l965).

  6. V. I. Dostovalova, F. K. Velichko, T. T. Vasil'eva, N. V. Kruglova, and R. Kh. Freidlina, Org. Magn. Res.,16, 251 (1981).

    Google Scholar 

  7. T. T. Vasil'va, L. F. Germanova, V. I. Dostovalova, B. V. Nelyubin, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 872 (1903).

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    T. T. Vasil'eva, L. F. Germanova, V. I. Dostovalova, B. V. Nelyubin & R. Kh. Freidlina

Authors
  1. T. T. Vasil'eva
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  2. L. F. Germanova
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  3. V. I. Dostovalova
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  4. B. V. Nelyubin
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  5. R. Kh. Freidlina
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2759–2765, December, 1983.

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Vasil'eva, T.T., Germanova, L.F., Dostovalova, V.I. et al. Step-by-step telomerization of propylene and 1-hexene by carbon tetrabromide. Russ Chem Bull 32, 2474–2479 (1983). https://doi.org/10.1007/BF00954478

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  • DOI: https://doi.org/10.1007/BF00954478

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