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Mechanism of palladium chloride-catalyzed hydrolytic cleavage of SI-AR bond in trimethylarylsilanes

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A kinetic and mechanistic study has been made of the cleavage of the silicon-aryl bond in trimethylarylsilanes, catalyzed by Li2PdCl4, and it has been shown that the catalyst of the reaction is the complex LiPdCl3.

  2. 2.

    The cleavage of the silicon-aryl bond in trimethylarylsilanes under the influence of Li2PdCl4, differs from the known reactions of silicon-aryl bond cleavage in that substituents have no appreciable effect.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of The USSR, Moscow

    I. S. Akhrem, N. M. Chistovalova, A. V. Malysheva & M. E. Vol'pin

Authors
  1. I. S. Akhrem
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  2. N. M. Chistovalova
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  3. A. V. Malysheva
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  4. M. E. Vol'pin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2696–2702, December, 1983.

We wish to express our appreciation to I. I. Moiseev for fruitful participation in the discussion of this work.

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Akhrem, I.S., Chistovalova, N.M., Malysheva, A.V. et al. Mechanism of palladium chloride-catalyzed hydrolytic cleavage of SI-AR bond in trimethylarylsilanes. Russ Chem Bull 32, 2417–2422 (1983). https://doi.org/10.1007/BF00954467

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  • DOI: https://doi.org/10.1007/BF00954467

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