Skip to main content
SpringerLink
Log in

Layer-by-layer method in dynamics of adsorption. communication 2. solution of reverse problem

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Feasibility has been demonstrated for a simple analytical or numerical solution of the reverse problem of adsorption dynamics, using the layer-by-layer method, in which the kinetic constants are expressed on a scale of length, for any adsorption isotherm, if a sufficient number of experimental exit curves are available.

  2. 2.

    A procedure is proposed for calculation of the kinetic constant the — layer of equilibrium adsorption Le-in the case of convex isotherms, from a single exit curve measured in the stage of parallel transfer.

  3. 3.

    In the example of solution of the reverse problem of adsorption dynamics for the system consisting of cyclohexane and activated carbon, confirmation has been obtained for the previous conclusion as to the independence of the kinetic constant of the degree of coverage in the adsorption of vapors of organic substances on activated carbons.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. V. Larin, Izv. Akad. Nauk SSSR, Ser. Khim., 236 (1983).

  2. A. V. Larin, Izv. Akad. Nauk SSSR, Ser. Khim., 1235 (1983).

  3. P. P. Zolotarev, in: Physical Adsorption in Microporous Adsorbents [in Russian], Nauka, Moscow (1979), No. 2, p. 59.

    Google Scholar 

  4. M. M. Dubinin, V. S. Kut'kov, A. V. Larin, K. M. Nikolaev, and N. S. Polyakov, Zh. Fiz. Khim.,56, 985 (1982).

    Google Scholar 

  5. M. M. Dubinin and L. V. Radushkevich, Dokl. Akad. Nauk SSSR,55, 331 (1947).

    Google Scholar 

  6. M. M. Dubinin, Zh. Fiz. Khim.,39, 1305 (1965).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Physical Chemistry, Academy of Sciences of the USSR, Moscow

    A. V. Larin

Authors
  1. A. V. Larin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2668–2672, December, 1983.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Larin, A.V. Layer-by-layer method in dynamics of adsorption. communication 2. solution of reverse problem. Russ Chem Bull 32, 2391–2395 (1983). https://doi.org/10.1007/BF00954461

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00954461

Keywords

Search

Navigation