Skip to main content
SpringerLink
Log in

Catalytic systems for oxidative chlorination of hydrocarbons. Communication 2. Study of the reaction in the copper-containing salt component-carrier system by the method of thermal analysis

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In copper-containing salt catalysts for oxidative chlorination on various carriers, catalysts with the same amount of applied salt component have a different surface composition as a result of the reaction with the carrier. The formation of surface melts is a function of the nature of the carrier and the concentration of the salt component.

  2. 2.

    “Separation” of the KCl·CuCl2 salt system with formation of surface states characteristic of KCl/carrier and CuCl2/carrier systems takes place on carriers with a developed surface.

  3. 3.

    Elimination of water molecules and hydroxyl groups from the surface of the carrier is significantly facilitated under the effect of the salt component.

  4. 4.

    Due to the reaction with the carrier, the salt component in the catalyst decomposes more easily than the individual salt system.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. I. G. Solomonik, I. I. Kurlyandskaya, V. Ya. Danyusheskii, and V. I. Yakerson, Izv. Akad. Nauk SSSR, Ser. Khim., 2175 (1984).

  2. D. Dollimore, Thermochim. Acta,50, 123 (1981).

    Google Scholar 

  3. G. N. Gaevskii, A. K. Potapovich, L. I. Lafer, and V. I. Yakerson, Izv. Akad. Nauk SSSR, Ser. Khim., 2198 (1981).

  4. N. S. Kozlov, M. I. Kozlyak, and L. P Dmitrieva, Izv. Akad. Nauk BSSR, Ser. Khim. Nauk, 12 (1982).

  5. A. Arcoya, A. Cortes, and X. L. Sedons, Can. J. Chem. Eng.,60, 55 (1982).

    Google Scholar 

  6. L. I. Heifets and A. V. Neimark, Multiphase Processes in Porous Media [Russian translation], Khimiya, Moscow (1982).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    I. G. Solomonik, I. I. Kurlyandskaya, V. Ya. Danyushevskii & V. I. Yakerson

  2. State Scientific-Research and Planning Institute of the Chlorine Industry, Moscow

    I. G. Solomonik, I. I. Kurlyandskaya, V. Ya. Danyushevskii & V. I. Yakerson

Authors
  1. I. G. Solomonik
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. I. Kurlyandskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. Ya. Danyushevskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. I. Yakerson
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2180–2185, October, 1984.

We would like to thank L. I, Virin for the mass spectrometric study of the systems and V. D. Nissenbaum for assistance in conducting the experiment.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Solomonik, I.G., Kurlyandskaya, I.I., Danyushevskii, V.Y. et al. Catalytic systems for oxidative chlorination of hydrocarbons. Communication 2. Study of the reaction in the copper-containing salt component-carrier system by the method of thermal analysis. Russ Chem Bull 33, 1988–1992 (1984). https://doi.org/10.1007/BF00954066

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00954066

Keywords

Search

Navigation