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Steric structure of some 2-halogenated ethylbenzenes

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    With the complex use of the methods of dipole moments, the Kerr effect, the Cotton-Mouton effect, and molecular mechanics, it was shown that the 2-halogenated ethylbenzenes studied in solutions of CC14 are an equilibrium mixture of approximately equally populated trans and gauche retainers on the C-C bond.

  2. 2.

    In both conformations, the plane of the aromatic ring is close to shielding of the C-H bond.

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Authors and Affiliations

  1. Kazan Branch, A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, USSR

    V. E. Kataev, S. G. Vul'fson, O. M. Dianova & A. N. Vereshchagin

Authors
  1. V. E. Kataev
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  2. S. G. Vul'fson
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  3. O. M. Dianova
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  4. A. N. Vereshchagin
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2014–2019, September, 1986.

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Kataev, V.E., Vul'fson, S.G., Dianova, O.M. et al. Steric structure of some 2-halogenated ethylbenzenes. Russ Chem Bull 35, 1831–1836 (1986). https://doi.org/10.1007/BF00954014

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  • DOI: https://doi.org/10.1007/BF00954014

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