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Effect of intramolecular rotational reorganization of reagents on the ratio between free energies of activation and reaction

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The relationship between the free energies of activation ΔG≠ and reaction ΔGo for proton transfer processes have been analyzed, taking into account the effect of hindered rotation of the reagents. We have shown that the considered effect can considerably affect the shape of the ΔG≠=f(ΔGo) curve.

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Literature cited

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Authors and Affiliations

  1. A. N. Frumkin Institute of Electrochemistry, Academy of Sciences of the USSR, Moscow

    É. D. German & A. M. Kuznetsov

Authors
  1. É. D. German
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  2. A. M. Kuznetsov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 77–81, January 1989.

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German, É.D., Kuznetsov, A.M. Effect of intramolecular rotational reorganization of reagents on the ratio between free energies of activation and reaction. Russ Chem Bull 38, 66–69 (1989). https://doi.org/10.1007/BF00953702

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  • DOI: https://doi.org/10.1007/BF00953702

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