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Synthesis of irregular lavandulyl series isoprenoids based on 4-phenylthio-3-methylbut-2Z-en-1-ol

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The dianion that is generated by a strong base from 4-phenylthio-3-methylbut-2Z-en-1-ol undergoes a predominantly γ-alkylation in the presence of terpenyl halides.

  2. 2.

    A simple method was found for synthesizing irregular isoprenoids of the lavandulol series.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. V. Veselovskii, V. A. Koptenkova & A. M. Moiseenkov

Authors
  1. V. V. Veselovskii
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  2. V. A. Koptenkova
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  3. A. M. Moiseenkov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 372–376, February, 1989.

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Veselovskii, V.V., Koptenkova, V.A. & Moiseenkov, A.M. Synthesis of irregular lavandulyl series isoprenoids based on 4-phenylthio-3-methylbut-2Z-en-1-ol. Russ Chem Bull 38, 321–324 (1989). https://doi.org/10.1007/BF00953621

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  • DOI: https://doi.org/10.1007/BF00953621

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