Conclusions
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1.
Hydrogenation of the acetylacetonates of Ni, Co, Cu, and Zn at atmospheric pressure and at 100 atm both on Ni and on NiM proceeded at a lower rate than the hydrogenation of pure acetylacetone. The rate of hydrogenation grew along the series of acetylacetonates Co < Zn ≤ Ni < Cu (Ni) and Co < Zn ≤ Cu < Ni (NiM).
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2.
Hydrogenation of acetylacetonates on a nickel catalyst modified with (+)-tartaric acid led to the formation of optically active products.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 838–841, April, 1983.
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Klabunovskii, E.I., Sokolova, N.P., Petrov, Y.I. et al. Asymmetric hydrogenation of acetylace tonates on raney nickel catalyst. Russ Chem Bull 32, 765–768 (1983). https://doi.org/10.1007/BF00953472
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DOI: https://doi.org/10.1007/BF00953472