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Nucleophilic addition to acetylenes in superbasic catalytic systems: XVIII. Vinylation of phenols and naphthols with acetylene

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Abstract

Phenols and naphthols react with acetylene in a superbasic system KOH-DMSO forming the corresponding aryl vinyl ethers in up to 80% yields.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    B. A. Trofimov, L. A. Oparina, N. A. Kolyvanov, O. V. Vysotskaya & N. K. Gusarova

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  1. B. A. Trofimov
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  2. L. A. Oparina
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  3. N. A. Kolyvanov
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  4. O. V. Vysotskaya
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  5. N. K. Gusarova
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Correspondence to B. A. Trofimov.

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Original Russian Text © B.A. Trofimov, L.A. Oparina, N.A. Kolyvanov, O.V. Vysotskaya, N.K. Gusarova, 2015, published in Zhurnal Organicheskoi Khimii, 2015, Vol. 51, No. 2, pp. 200–206.

For communication XVII, see [1].

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Trofimov, B.A., Oparina, L.A., Kolyvanov, N.A. et al. Nucleophilic addition to acetylenes in superbasic catalytic systems: XVIII. Vinylation of phenols and naphthols with acetylene. Russ J Org Chem 51, 188–194 (2015). https://doi.org/10.1134/S1070428015020086

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  • DOI: https://doi.org/10.1134/S1070428015020086

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