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Chemiluminescence during the oxidation of histamine by potassium bromate activated with terbium

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We have detected and investigated chemiluminescence (CL) during the oxidation of the biologically active amine, histamine, which can be used for analytical purposes.

  2. 2.

    The primary emitter of the chemiluminescence, which is most probably imidazolylacetaldehyde, is formed in the triplet state with an energy in the range from 2.60 to 3.98 eV.

  3. 3.

    Tb3+ ions do not accelerate the oxidation of histamine but activate the chemiluminescence via an energy transfer mechanism.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Branch, Academy of Sciences of the USSR, Ufa

    G. L. Sharipov, G. V. Kosareva, L. A. Fukalova & A. D. Karavaev

  2. Ufimsk Institute of Hygiene and Professional Illnesses, USSR

    G. L. Sharipov, G. V. Kosareva, L. A. Fukalova & A. D. Karavaev

Authors
  1. G. L. Sharipov
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  2. G. V. Kosareva
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  3. L. A. Fukalova
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  4. A. D. Karavaev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khmicheskaya, No. 4, pp. 770–777, April, 1983.

The authors thank V. P. Kazakov, under the initiative of whom the present work was carried out, for his useful discussion of the results.

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Sharipov, G.L., Kosareva, G.V., Fukalova, L.A. et al. Chemiluminescence during the oxidation of histamine by potassium bromate activated with terbium. Russ Chem Bull 32, 702–708 (1983). https://doi.org/10.1007/BF00953460

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  • DOI: https://doi.org/10.1007/BF00953460

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