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Investigation of the Solution Phase Chemi-Luminescence of 1,2,4-triazole Derivatives

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Chemistry of Heterocyclic Compounds Aims and scope

We discovered and studied the chemiluminescence occurring during the oxidation of 3-bromo-5-hydrazino-1-(thietan-3-yl)-1H-1,2,4-triazole with superoxide anion. The chemiluminescence wavelength interval was 400-590 nm with the maxima (at 436 and 540 nm) matching the peak fluorescence wavelengths of the reaction products. The possible reaction products were determined by NMR spectroscopy, mass spectrometry, IR and UV spectroscopy. The quantum yield of chemiluminescence was 10-9 E/mol.

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The work was performed with financial support from Materials Science and Chemistry Division of Russian Academy of Sciences (program OKh-01). The authors would like to express their gratitude to the Collective Use Center "Chemistry", Institute of Organic Chemistry, Ural Scientific Center of the Russian Academy of Sciences for recording the NMR, IR, and UV spectra.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ural Scientific Center, Russian Academy of Sciences, 71 Oktyabrya Ave., Ufa, 450054, Russia

    R. R. Kayumova, R. R. Muslukhov, M. F. Abdullin, A. V. Mamykin & S. L. Khursan

  2. Bashkir State Medical University, 3 Lenina St., Ufa, 450000, Russia

    E. E. Klen, F. A. Khaliullin & G. F. Magadeeva

Authors
  1. R. R. Kayumova
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  2. R. R. Muslukhov
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  3. M. F. Abdullin
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  4. E. E. Klen
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  5. F. A. Khaliullin
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  6. G. F. Magadeeva
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  7. A. V. Mamykin
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  8. S. L. Khursan
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Corresponding author

Correspondence to A. V. Mamykin.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 1062-1068, July, 2014.

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Kayumova, R.R., Muslukhov, R.R., Abdullin, M.F. et al. Investigation of the Solution Phase Chemi-Luminescence of 1,2,4-triazole Derivatives. Chem Heterocycl Comp 50, 979–985 (2014). https://doi.org/10.1007/s10593-014-1553-9

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  • DOI: https://doi.org/10.1007/s10593-014-1553-9

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