Conclusions
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1.
cis- and trans-2-Alkyl(aryl)-cis-1-thiahydrindanes have been obtained for the first time free from traces of structural isomers.
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2.
cis-1-Thiahydrindane and trans-2-alkyl(aryl)-cis-1-thiahydrindanes are present in solution predominantly in conformations in which H9 is equatorial in the cyclohexane ring, whereas cis-2-alkyl(aryl)-cis-1-thiahydrindanes have the conformation in which H9 is axial.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2352–2357, October, 1988.
The authors thank I. I. Chervin for help in obtaining and interpreting the spectra.
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Volynskii, N.P., Zegel'man, L.A. & Smirnov, M.B. Synthesis of 2-alkyl(aryl)-cis-1-thiahydrindanes. Russ Chem Bull 37, 2118–2122 (1988). https://doi.org/10.1007/BF00953417
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DOI: https://doi.org/10.1007/BF00953417