Conclusions
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1.
An effective reduction of halogen-containing hydrocarbons at the C-Hal bond was carried out by means of i-Bu2AlH in the presence of catalytic amounts of Ti, Zr, and Hf complexes.
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2.
A partial transformation of halobenzenes and bromocyclohexane into hexane by the action of i-Bu2AlH and catalytic amounts of Cp2TiCl2 under mild conditions was noted for the first time.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2332–2334, October, 1988.
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Dzhemilev, U.M., Gaisin, R.L. Effective reduction of halogen-containing hydrocarbons by diisobutyl aluminum hydride in the presence of transition metal hydrides. Russ Chem Bull 37, 2099–2102 (1988). https://doi.org/10.1007/BF00953413
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DOI: https://doi.org/10.1007/BF00953413