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Hydrogenation of aromatic hydrocarbons in a mixture with thiophene on sulfided Pd/Al2O3 catalysts

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Abstract

The activity and stability of aluminum-palladium catalysts in the hydrogenation of aromatic hydrocarbons mixed with thiophene were studied. The catalysts were obtained by impregnation of γ-A2O3 with aqueous solutions of salts of palladium complexes. Preliminary sulfiding followed by oxidative activation of Pd/Al2O3 catalysts were found to favor the formation of such palladium state on the surface at which the hydrogenation of aromatic hydrocarbons in the presence of sulfur-containing impurities proceeds without a noticeable change in the activity with time. IR spectroscopy showed that the palladium metal surface fragments forming CO complexes with a characteristic absorption band at 1998 cm–1 are resistant to poisoning with sulfur-containing compounds in the hydrogenation of aromatic hydrocarbons.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    A. L. Tarasov

  2. Joint Institute for High Temperatures, Russian Academy of Sciences, Build. 2, 13 Izorskaya ul., 125412, Moscow, Russian Federation

    O. V. Malova & I. I. Lishchiner

Authors
  1. A. L. Tarasov
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  2. O. V. Malova
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  3. I. I. Lishchiner
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Correspondence to A. L. Tarasov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2786—2790, December, 2015.

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Tarasov, A.L., Malova, O.V. & Lishchiner, I.I. Hydrogenation of aromatic hydrocarbons in a mixture with thiophene on sulfided Pd/Al2O3 catalysts. Russ Chem Bull 64, 2786–2790 (2015). https://doi.org/10.1007/s11172-015-1226-6

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  • DOI: https://doi.org/10.1007/s11172-015-1226-6

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