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Concentration dependence and effect of oxygen on the primary phototrans-formation processes of khinifur

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The decomposition of khinifur in aqueous solutions proceeds according to two parallel paths: direct photodecomposition from the first singlet activated state (monomolecular path) and reaction of the molecule in the triplet state with a molecule in the initial state (bimolecular path).

  2. 2.

    The first path does not depend on the pressure of oxygen in the solution, while the second path is inhibited by oxygen.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    N. K. Tatarskaya, M. A. Zhurav, S. M. Smirnov, I. A. Degterev, V. F. Tarasov, Yu. E. Borisevich & G. E. Zaikov

Authors
  1. N. K. Tatarskaya
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  2. M. A. Zhurav
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  3. S. M. Smirnov
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  4. I. A. Degterev
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  5. V. F. Tarasov
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  6. Yu. E. Borisevich
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  7. G. E. Zaikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 804–809, April, 1989.

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Tatarskaya, N.K., Zhurav, M.A., Smirnov, S.M. et al. Concentration dependence and effect of oxygen on the primary phototrans-formation processes of khinifur. Russ Chem Bull 38, 722–726 (1989). https://doi.org/10.1007/BF00953279

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  • DOI: https://doi.org/10.1007/BF00953279

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