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Negative-ion mass spectra of heteroorganic compounds of group IV

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The dissociative resonance capture of electrons by the molecules of heteroorganic compounds of group IV was studied. It was shown that a new resonance state is observed with the introduction of a vinyl substituent. The nonadditive increase in the relative cross section for the formation of the negative ion with increase in the number of vinyl substituents is due to the stabilization of the molecule negative ion by σ* -π* interaction.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Branch of the Academy of Sciences of the USSR, Ufa

    I. I. Furlei, V. K. Mavrodiev, I. M. Salimgareeva & N. G. Bogatova

Authors
  1. I. I. Furlei
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  2. V. K. Mavrodiev
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  3. I. M. Salimgareeva
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  4. N. G. Bogatova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 566–571, March, 1986.

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Furlei, I.I., Mavrodiev, V.K., Salimgareeva, I.M. et al. Negative-ion mass spectra of heteroorganic compounds of group IV. Russ Chem Bull 35, 514–518 (1986). https://doi.org/10.1007/BF00953217

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  • DOI: https://doi.org/10.1007/BF00953217

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