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1H NMR Spectra of dichloro and dihydroxy derivatives of methylcyclosiloxanes

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Assignment of lines has been performed in the1H NMR spectra of dichloro and dihydroxy derivatives of methylcyclosiloxanes.

  2. 2.

    Additivity has been demonstrated for the chemical shifts of CH3 group protons in dichloromethylcyclosiloxanes, and the increments of chemical shift have been obtained for 8-, 10-, 12-, 14-, and 16-membered rings. It has been established that the chemical shifts in the spectra of the dihydroxy derivatives are nonadditive.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    B. D. Lavrukhin, N. N. Makarova & A. A. Zhdanov

Authors
  1. B. D. Lavrukhin
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  2. N. N. Makarova
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  3. A. A. Zhdanov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 559–566, March, 1986.

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Lavrukhin, B.D., Makarova, N.N. & Zhdanov, A.A. 1H NMR Spectra of dichloro and dihydroxy derivatives of methylcyclosiloxanes. Russ Chem Bull 35, 508–514 (1986). https://doi.org/10.1007/BF00953216

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  • DOI: https://doi.org/10.1007/BF00953216

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