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Determination of the quantum yields of photodissociation of aniline derivatives

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Cleavage of the N-H bond with the formation of H atoms and aminyl radicals is the only photochemical process in the irradiation of anilines in heptane with light) the quantum yields of this process were determined.

  2. 2.

    The quantum yields of photodissociation increase sharply with an increase in the excitation energy.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    Sh. Ruziev, Ya. N. Malkin & V. A. Kuz'min

Authors
  1. Sh. Ruziev
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  2. Ya. N. Malkin
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  3. V. A. Kuz'min
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 537–541, March, 1986.

We would like to thank S. N. Kozlova for calibration of the PMT-2 lamp with respect to H2.

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Ruziev, S., Malkin, Y.N. & Kuz'min, V.A. Determination of the quantum yields of photodissociation of aniline derivatives. Russ Chem Bull 35, 488–492 (1986). https://doi.org/10.1007/BF00953210

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  • DOI: https://doi.org/10.1007/BF00953210

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