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Convenient method for the selective oxidation of sulfide sulfur in alkylmercaptoalkyl esters of thio- and dithioacids of phosphorus

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A general method has been developed for the oxidation of sulfide sulfur in S-mercaptoalkyl esters of thio- and dithioacids of phosphorus to the sulfoxides and sulfones.

  2. 2.

    The oxidative activation metabolites of O-ethyl-S-(methoxycarbonylmethylmercaptomethyl) methyldithiophosphonate and its monothio analog, and the hydrolytic detoxification metabolite of the former, have been synthesized.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    T. A. Mastryukova, G. V. Zhdanova, A. É. Shipov & M. I. Kabachnik

Authors
  1. T. A. Mastryukova
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  2. G. V. Zhdanova
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  3. A. É. Shipov
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  4. M. I. Kabachnik
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1384–1389, June, 1983.

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Mastryukova, T.A., Zhdanova, G.V., Shipov, A.É. et al. Convenient method for the selective oxidation of sulfide sulfur in alkylmercaptoalkyl esters of thio- and dithioacids of phosphorus. Russ Chem Bull 32, 1255–1260 (1983). https://doi.org/10.1007/BF00953168

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  • DOI: https://doi.org/10.1007/BF00953168

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