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Variation of the methylene group's contribution to the total energy of sorption as a function of its proximity to the functional group in a homologous series during chromatography

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The energy contributions of the methylene groups of n-alkyl chains to the total free energy of solution in Apiezon L and Carbowax-1000 were evaluated by gas-liquid chromatography in the following homologous series: n-alkanes, amines, alcohols, n-alkyl formates, n-alkyl methyl ketones, and thioethers.

  2. 2.

    The calculated methylene group contribution depends on its position in the chain, once the role of the dispersion interactions has been established; the CH2 groups in the β-and γ-positions with respect to the functional group show the highest contributions.

  3. 3.

    An equation is proposed for the calculation of the contribution of each of the n-alkyl radicals in a given series of homologs to the free energy of solution.

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Literature cited

  1. J. Novak and J. Ruzickova, J. Chromatogr.,91, 79 (1974).

    Google Scholar 

  2. D. H. Desty and W. T. Swanton, J. Phys. Chem.,65, 766 (1961).

    Google Scholar 

  3. R. V. Golovnya and D. N. Grigor'eva, Izv. Akad. Nauk SSSR, Ser. Khim., 1825 (1981).

  4. W. O. McReynolds, Gas Chromatographic Retention Data, Preston: Technical Abstract Co., Evanston (1966).

    Google Scholar 

  5. R. V. Golovnya, V. G. Garbuzov, and T. A. Misharina, Izv. Akad. Nauk SSSR, Ser. Khim., 2266 (1976).

  6. R. V. Golovnya and I. L. Zhuravleya, Chromatographia,6, 766 (1961).

    Google Scholar 

  7. R. V. Golovnya and D. N. Grigor'eva, Izv. Akad. Nauk SSSR, Ser. Khim., 1246 (1983).

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Authors and Affiliations

  1. A. M. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    R. V. Golovnya & D. N. Grigor'eva

Authors
  1. R. V. Golovnya
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  2. D. N. Grigor'eva
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1240–1246, June, 1983.

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Golovnya, R.V., Grigor'eva, D.N. Variation of the methylene group's contribution to the total energy of sorption as a function of its proximity to the functional group in a homologous series during chromatography. Russ Chem Bull 32, 1119–1123 (1983). https://doi.org/10.1007/BF00953139

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  • DOI: https://doi.org/10.1007/BF00953139

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