Conclusions
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1.
The radiolysis of a series of individual perfluorinated compounds leads to the formation of radicals which are stable not only in the liquid phase in solutions but also in the gas phase.
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2.
The discovered stable radicals do not react with oxygen either during prolonged storage or during γ irradiation at 300°K.
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3.
The radiolysis of the compounds in the liquid and solid phases leads to the formation of various unstable radicals.
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B. L. Tumanskii. N. N. Bubnov, V. R. Polishchuk, and S. P. Solodovnikov, Izv. Akad. Nauk SSSR, Ser. Khim., 2222 (1981).
S. R. Allayarov, S. V. Demidov, D. P. Kiryukhin, A. I. Mikhailov, and I. M. Barkalov, Khim. Vys. Energ.,17, 178 (1983).
S. R. Allayarov, I. M. Barkalov, V. I. Gol'danskii, S. V. Demidov, D. P. Kiryukhin, and A. I. Mikhailov, Izv. Akad. Nauk SSSR, Ser. Khim., 1449 (1983).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1225–1228, June, 1983.
The authors express their gratitude to Academician I. L. Knunyants for assistance in the work and for valuable discussions.
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Allayarov, S.R., Barkalov, I.M., Gol'danskii, V.I. et al. Formation of stable radicals from organofluorine compounds. Russ Chem Bull 32, 1105–1107 (1983). https://doi.org/10.1007/BF00953135
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DOI: https://doi.org/10.1007/BF00953135