Conclusions
-
1.
The kinetics of reactions of alkali metal salts of 9-carbomethoxy- and 9-cyanofluorene with para-nitrofluorobenzene and of Me3SnM with pentafluoropyridine have been studied.
-
2.
In the case of carbanions the free anions are more reactive, while in the case of Me3SnM the corresponding tight (contact) ion pairs are more reactive.
-
3.
The effect of the leaving group (on reactivity) was investigated using the reactions of pentafluorochlorobenzene with the K salts of 9-carbomethoxyfluorene and cyclopentadienylirondicarbonyl anions as examples.
-
4.
The reaction mechanism has been shown to depend on the nature of the nucleophile.
Similar content being viewed by others
Literature cited
G. A. Artamkina, A. Yu. Mil'chenko, I. P. Beletskaya, and O. A. Reutov, J. Organomet. Chem.,311, 199 (1986).
G. A. Artamkina, A. Yu. Mil'chenko, I. P. Beletskaya, and O. A. Reutov, J. Organomet. Chem.,321, 371 (1987).
É. S. Petrov, Ph.D. Dissertation, Moscow (1977), p. 266.
F. G. Bordwell and D. L. Hughes, J. Org. Chem.,45, 3314 (1980).
F. Cacace, M. Speranga, A. P. Wolf, and R. R. Macgregor, J. Fluor. Chem.,21, 145 (1982).
J. Burdon, W. B. Hollyhead, C. R. Patrick, and K. V. Wilson, J. Chem. Soc., 6375 (1965).
A. A. Solov'yanov, I. P. Beletskaya, and O. A. Reutov, Zh. Org. Khim.,19, 1822 (1983).
A. A. Solov'yanov, I. P. Beletskaya, and O. A. Reutov, Zh. Org. Khim.,18, 1373 (1982).
C. Germain, Tetrahedron,32, 2839 (1976).
A. T. Weibel and J. P. Oliver, J. Organomet. Chem.,82, 281 (1974).
R. J. Hogan, P. A. Sherr, A. T. Weibel, and J. P. Oliver, J. Organomet. Chem.,85, 265 (1975).
F. G. Bordwell and D. L. Hughes, J. Am. Chem. Soc.,108, 5991 (1986).
J. F. Bunnet and R. A. Zahler, Chem. Rev.,49, 273 (1951).
J. Miller, Aromatic Nucleophilic Substitution, Elsevier, Amsterdam-London-New York (1986).
M. R. Crampton, T. D. Kee, and J. R. Wilcock, Can. J. Chem.,64, 1714 (1986).
V. Maĉhacek, V. Stérba, and A. Lyska, Collect. Czech. Chem. Commun.,52, 132 (1987).
M. I. Bruce, D. N. Sharrock, and F. G. A. Stone, J. Chem. Soc., A, 680 (1970).
D. Vorlander and A. Pritgche, Chem. Ber.,46, 1793 (1913).
C. J. Collins, J. Am. Chem. Soc.,70, 2418 (1948).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2826–2832, December, 1988.
Rights and permissions
About this article
Cite this article
Artamkina, G.A., Mil'chenko, A.Y., Beletskaya, I.P. et al. Effect of nature of the nucleophile on the mechanism of nucleophilic aromatic substitution reactions involving fluorenyl and trimethylstannyl anions. Russ Chem Bull 37, 2550–2556 (1988). https://doi.org/10.1007/BF00952638
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00952638