Conclusions
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1.
The intramolecular Khand-Pauson reaction is substantially accelerated when it is carried out on the surface of a Chromatographic adsorbent in the absence of a solvent.
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2.
A method has been developed for the preparation of substituted 3-oxabicyclo[3.3.0]-oct-5-en-7-ones, by cyclization of the dicobalt hexacarbonyl complexes of allyl propargyl ethers.
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3.
A novel cyclization reaction of dicobalt hexacarbonyl complexes has been found, which provides a convenient synthetic route to 4-hydroxymethylcyclopent-2-en-1-ones.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2802–2812, December, 1988.
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Smit, V.A., Simonyan, S.O., Tarasov, V.A. et al. Intramolecular cyclization of dicobalt hexacarbonyl complexes of allyl propyl ethers on adsorbent surfaces. A convenient mode of preparation of 3-oxabicyclo[3.3.0]octenes and 4-hydroxymethylcyclopentenone derivatives. Russ Chem Bull 37, 2526–2535 (1988). https://doi.org/10.1007/BF00952633
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DOI: https://doi.org/10.1007/BF00952633