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Oxidative addition products in reactions of heteroorganic compounds with substituted o-quinones

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The products of the oxidative 1,4-addition formed in the reaction of diheteroorganic compounds with sterically hindered o-quinones react readily with organic oxidants.

  2. 2.

    The types of reactions of o-hemiquinolates of Group IVB elements are determined by the tendency to eliminate alkyl and aryl groups from the heteroatom under the influence of the unpaired electron of the free-radical ligand.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemistry, Academy of Sciences of the USSR, Gor'kii

    G. A. Razuvaev, G. A. Abakumov, E. N. Gladyshev, P. Ya. Bayushkin & V. A. Tsaryapkin

Authors
  1. G. A. Razuvaev
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  2. G. A. Abakumov
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  3. E. N. Gladyshev
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  4. P. Ya. Bayushkin
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  5. V. A. Tsaryapkin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2138–2144, September, 1982.

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Razuvaev, G.A., Abakumov, G.A., Gladyshev, E.N. et al. Oxidative addition products in reactions of heteroorganic compounds with substituted o-quinones. Russ Chem Bull 31, 1888–1893 (1982). https://doi.org/10.1007/BF00952395

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  • DOI: https://doi.org/10.1007/BF00952395

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