Conclusions
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1.
The interaction of O-mesitylenesulfonyl-, O-mesitoyl-, O-(2,4-dinitrophenyl)-, and O-picrylacetoximes with n-butylamine has been investigated. It was shown that it was possible to use only the first two esters for the synthesis of diaziridines based on ketones.
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2.
The use of esters of acetaldoximes in reactions with amines is not promising for the synthesis of diaziridines.
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3.
Nucleophilic substitution of the oxime group by the butylamine group occurred in the reaction of butylamine with O-(2,4-dinitrophenyl)- and O-picryloximes.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2107–2110. September, 1982.
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Makhova, N.N., Petukhova, V.Y. & Khmel'nitskii, L.I. Synthesis of diaziridines from oxime esters. Russ Chem Bull 31, 1858–1862 (1982). https://doi.org/10.1007/BF00952389
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DOI: https://doi.org/10.1007/BF00952389