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NMR spectroscopic study of conjugation effects Communication 19. Electronic effects in trialkyl phenoxy derivatives of silicon, germanium, and tin

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A complete analysis has been performed on the13C-satellite13C-{1H} NMR spectra of the benzene ring of trialkyl phenoxy derivatives of Si, Ge, and Sn.

  2. 2.

    In this series of compounds, the degree of orbital overlapping of the 2p-electrons of the oxygen atom with the π-system of the benzene ring is practically independent of steric interactions.

  3. 3.

    Only the 3d-orbital of the Si atom has appreciable π-acceptor properties in interaction with the unshared electron pairs of oxygen.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    L. B. Krivdin, G. A. Kalabin, R. G. Mirskov & S. P. Solov'eva

  2. A. A. Zhdanov Irkutsk State University, USSR

    L. B. Krivdin, G. A. Kalabin, R. G. Mirskov & S. P. Solov'eva

Authors
  1. L. B. Krivdin
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  2. G. A. Kalabin
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  3. R. G. Mirskov
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  4. S. P. Solov'eva
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2038–2042, September, 1982.

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Krivdin, L.B., Kalabin, G.A., Mirskov, R.G. et al. NMR spectroscopic study of conjugation effects Communication 19. Electronic effects in trialkyl phenoxy derivatives of silicon, germanium, and tin. Russ Chem Bull 31, 1799–1802 (1982). https://doi.org/10.1007/BF00952380

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  • DOI: https://doi.org/10.1007/BF00952380

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