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Kinetics of the thermal decomposition of dimethyltriazanium chloride and nitrate

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The kinetics of the thermal decomposition of dimethyltriazanium (DMTA) chloride and nitrate is described by a first-order autocatalysis equation.

  2. 2.

    The major contribution to autoacceleration of decomposition is made by the transfer of salts to the liquid phase as a result of their solubility in their own decomposition products.

  3. 3.

    The decomposition of DMTA salts proceeds by the elimination of an NH2 + cation and methane from the [(CH3)2N(NH2)2]+ cation.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    Yu. I. Rubtsov, L. P. Andrienko, K. V. Titova & E. N. Loginova

  2. Institute of New Chemical Problems, Academy of Sciences of the USSR, Chernogolovka

    Yu. I. Rubtsov, L. P. Andrienko, K. V. Titova & E. N. Loginova

Authors
  1. Yu. I. Rubtsov
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  2. L. P. Andrienko
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  3. K. V. Titova
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  4. E. N. Loginova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1953–1957, September, 1982.

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Rubtsov, Y.I., Andrienko, L.P., Titova, K.V. et al. Kinetics of the thermal decomposition of dimethyltriazanium chloride and nitrate. Russ Chem Bull 31, 1725–1729 (1982). https://doi.org/10.1007/BF00952363

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  • DOI: https://doi.org/10.1007/BF00952363

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