Conclusions
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1.
A series of hydride complexes of nickel, palladium, and platinum was obtained by oxidative-addition reactions of zerovalent triphenylphosphine complexes of the metals with pentafluorophenyl-substituted germanes. The Pt-H groups in the obtained compounds were distinguished by low reactivity.
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2.
A stable complex with a Pt-Ge-Ge-Hg chain was synthesized by the reaction of HPt(PPh3)2-Ge(C6F5)2-Ge(C6F5)2H with diethylmercury.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1854–1858, August, 1979.
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Bochkarev, M.N., Maiorova, L.P., Skobeleva, S.E. et al. Some reactions of pentafluorophenyl-substituted germanes with triphenylphosphine complexes of platinum. Russ Chem Bull 28, 1717–1722 (1979). https://doi.org/10.1007/BF00951001
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DOI: https://doi.org/10.1007/BF00951001