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Synthesis of nitrobenzene radical anion in a matrix and its IR absorption spectrum

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The radical anion of nitrobenzene is prepared by reacting atomic sodium with nitrobenzene in a nitrobenzene matrix at 77°K.

  2. 2.

    For the first time, the complete IR spectrum of the crystalline nitrobenzene radical anion has been measured in the 400–3800 cm−1 range.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1785–1787, August, 1980.

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Baronetskii, A.O., Kuz'yants, G.M. Synthesis of nitrobenzene radical anion in a matrix and its IR absorption spectrum. Russ Chem Bull 29, 1267–1269 (1980). https://doi.org/10.1007/BF00950570

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  • DOI: https://doi.org/10.1007/BF00950570

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