Conclusions
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1.
Conditions have been found for an effective reaction between o-palladized N,N-dimethylbenzylamine and styrene.
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2.
An unusually strong salt effect was observed in this reaction.
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3.
Two reaction products were formed simultaneously: 2-dimethylaminomethylstilbene and its palladized derivative. Conditions for the preferential formation of each product were found.
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Literature cited
J. Tsuji, Acc. Chem. Res.,2, 144 (1969).
M. Julia, M. Duteil, and J. Y. Lallemand, J. Organomet. Chem.,102, 239 (1975).
R. A. Holton, Tetrahedron Lett., 355 (1977).
H. Horino and N. Inoue, Tetrahedron Lett., 2403 (1979).
C. H. Chao, D. W. Hart, R. Bau, and R. F. Heck, J. Organomet. Chem.,179, 301 (1979).
T. Izumi, K. Endo, O. Saito, I. Shimizu, M. Maemura, and A. Kasahara, Bull. Chem. Soc. Jpn.,51, 663 (1978).
A. Kasahara, T. Izumi, and H. Watabe, Bull. Chem. Soc. Jpn.,52, 957 (1979).
V. I. Sokolov, L. L. Troitskaya, and O. A. Reutov, Dokl. Akad. Nauk SSSR,246, 124 (1979); J. Organomet. Chem.,182, 537 (1979).
S. I. Kamiyama, T. Kimura, A. Kasahara, T. Izumi, and M. Maemura, Bull. Chem. Soc. Jpn.,52, 142 (1979).
A. K. Yatsimirsky, A. D. Ryabov, and I. V. Berezin, J. Mol. Catal.,5, 399 (1979).
A. C. Cope and E. C. Friedrich, J. Am. Chem. Soc.,90, 909 (1968).
B. Crociani, T. Boschi, P. Pietropaolo, and U. Belluco, J. Chem. Soc., A, 531 (1970).
C. J. Timmons and E. S. Stern, Gillam and Stern's: Introduction to Electronic Absorption Spectroscopy in Organic Chemistry, St. Martin's Press (1971).
I. Omae, Chem. Rev.,79, 287 (1979).
E. S. Ashby and S. A. Noding, J. Org. Chem.,44, 4371 (1979).
G. Henrici-Olive and S. Olive, Coordination and Catalysis, International Publications Service (1977).
P. M. Henry, Adv. Organomet. Chem.,13, 363 (1975).
L. G. Volkova, I. Yu. Levitin, and M. E. Vol'pin, Usp. Khim.,44, 1271 (1975).
T. A. Stephenson, S. M. Morehouse, A. R. Powell, J. P. Heffer, and G. Wilkinson, J. Chem. Soc., 3632 (1965).
R. Battino and H. L. Clever, Chem. Rev.,66, 395 (1966).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1378–1383, June, 1981.
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Ryabov, A.D., Yatsimirskii, A.K. & Berezin, I.V. Reaction between o-palladized N,N-dimethylbenzylamine and styrene. Russ Chem Bull 30, 1103–1107 (1981). https://doi.org/10.1007/BF00950305
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DOI: https://doi.org/10.1007/BF00950305