Conclusions
The oxides of dimethyl(bromomethyl)- and dimethyl(iodomethyl)phosphines exist as equilibrium mixtures of conformer pairs in solution, the form predominating in nonpolar solvents being that in which the phosphoryl and carbon-halogen bonds are in trans orientation.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1292–1296, June, 1981.
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Raevskii, O.A., Mumzhieva, N.G., Kron, T.E. et al. Conformational analysis of dimethyl(bromomethyl)- and dimethyl(iodomethyl)phosphine oxides. Russ Chem Bull 30, 1026–1030 (1981). https://doi.org/10.1007/BF00950286
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DOI: https://doi.org/10.1007/BF00950286