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Structural and stereochemical factors in the mass spectrometry of monocyclic hydrocarbons with geminal substituents

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The mass spectra of geminally substituted monocyclic hydrocarbons of the composition C8H16-C11H22 were studied.

  2. 2.

    An analogy in the principles of the decomposition of the molecular ions of geminally substituted cyclohexanes and cyclohexanes not having a geminal group in the molecule was established, as well as for the influence of stereochemical factors on the quantitative pattern of the mass spectra of the structural isomers.

  3. 3.

    The comparative characteristics of the decomposition, under electron impact, of geminally substituted hydrocarbons of the cyclohexane and cyclopentane series were given.

  4. 4.

    Diagnostic indexes for the identification of structural isomers were shown.

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Literature cited

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Authors and Affiliations

  1. Institute of Geology and Development of Combustible Minerals, Ministry of the Oil Industry, Academy of Sciences of the USSR, Moscow

    L. S. Golovkina, G. V. Rusinova, S. S. Berman & Al. A. Petrov

Authors
  1. L. S. Golovkina
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  2. G. V. Rusinova
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  3. S. S. Berman
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  4. Al. A. Petrov
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Additional information

Translated from Izvestiya Academii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1540–1547, July, 1985.

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Golovkina, L.S., Rusinova, G.V., Berman, S.S. et al. Structural and stereochemical factors in the mass spectrometry of monocyclic hydrocarbons with geminal substituents. Russ Chem Bull 34, 1409–1416 (1985). https://doi.org/10.1007/BF00950140

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  • DOI: https://doi.org/10.1007/BF00950140

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