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Alkylation of trimethylchloro- and dimethyldichlorosilanes using higher trialkylaluminums

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A study was carried out on the alkylation of trimethylchloro- and dimethyldichlorosilanes by higher trialkylaluminums containing linear and cycloalkenyl groups and a bulky alicyclic group. The catalytic effect of transition metal salts was studied for the alkylation reaction in the case of trihexylaluminum; TiCl4 was found to demonstrate the greatest activity.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Branch, Academy of Sciences of the USSR, Ufa

    A. V. Kuchin, A. Yu. Spivak, G. A. Tolstikov & V. N. Yur'ev

Authors
  1. A. V. Kuchin
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  2. A. Yu. Spivak
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  3. G. A. Tolstikov
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  4. V. N. Yur'ev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 910–913, April, 1982.

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Kuchin, A.V., Spivak, A.Y., Tolstikov, G.A. et al. Alkylation of trimethylchloro- and dimethyldichlorosilanes using higher trialkylaluminums. Russ Chem Bull 31, 803–806 (1982). https://doi.org/10.1007/BF00950024

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