Conclusions
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1.
Charge-transfer complexes of cyclopropyl aryl ethers (CAE) with tetracyanoethylene are of the π,π type (donor center — benzene ring) and with iodine are of the n,σ type (donor center — oxygen atom).
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2.
In the charge-transfer state in CAE participation of the gem-dichlorocyclopropane ring in the conjugation is not very large, and the electronic effects of the cyclopropane ring is transmitted mainly by the inductive -I mechanism.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2750–2754, December, 1980.
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Sennikov, P.G., Kuznetsov, V.A., Egorochkin, A.N. et al. Study of the charge-transfer complexes of cyclopropyl aryl ethers with different acceptors by electronic absorption spectroscopy. Russ Chem Bull 29, 1925–1928 (1980). https://doi.org/10.1007/BF00949658
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DOI: https://doi.org/10.1007/BF00949658