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Organoboron compounds.

377. Synthesis of 3-borahomoadamantane complexes

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    3-Borahomoadamantane was obtained from tetrahydrofuran-1-boraadamantane and trimethylammonium methylide as the complex with trimethylamine, tetrahydrofuran, and pyridine.

  2. 2.

    The acidolysis of trimethylamine-3-borahomoadamantane gave cis-5-ethyl-1, 3-dimethylcyclohexane.

  3. 3.

    3-Homoadamantanol was synthesized by the carbonylation of tetrahydrofuran-3-borahomoadamantane with CO.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    B. M. Mikhailov, N. N. Govorov, Ya. A. Angelyuk, V. G. Kiselev & M. I. Struchkova

Authors
  1. B. M. Mikhailov
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  2. N. N. Govorov
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  3. Ya. A. Angelyuk
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  4. V. G. Kiselev
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  5. M. I. Struchkova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1621–1626, July, 1980.

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Mikhailov, B.M., Govorov, N.N., Angelyuk, Y.A. et al. Organoboron compounds.. Russ Chem Bull 29, 1164–1169 (1980). https://doi.org/10.1007/BF00949176

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  • DOI: https://doi.org/10.1007/BF00949176

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