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Biscyclopentadienylzirconium(IV) hydridoalumohydride, its reaction with diborane and the synthesis of [(η5-C5H5)2ZrIV(BH4){H2Al(BH4)2}]

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A new method was developed for the synthesis of biscyclopentadienylzirconium(IV) hydroalumohydride, Cp2Zr(H)AlH by the reaction of Cp2Zr(BH4)2 with LiAlH4.

  2. 2.

    The addition of up to three BH3 groups at Al-H and Zr-H bonds is observed in the reaction of Cp2Zr(H)AlH4, with diborane, depending on the reaction conditions.

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Authors and Affiliations

  1. Institute of New Chemical Problems, Academy of Sciences of the USSR, Chernogolovka

    V. D. Sasnovskaya, L. V. Titov & V. Ya. Rosolovskii

Authors
  1. V. D. Sasnovskaya
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  2. L. V. Titov
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  3. V. Ya. Rosolovskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1408–1412, June, 1984.

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Sasnovskaya, V.D., Titov, L.V. & Rosolovskii, V.Y. Biscyclopentadienylzirconium(IV) hydridoalumohydride, its reaction with diborane and the synthesis of [(η5-C5H5)2ZrIV(BH4){H2Al(BH4)2}]. Russ Chem Bull 33, 1297–1301 (1984). https://doi.org/10.1007/BF00949005

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  • DOI: https://doi.org/10.1007/BF00949005

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