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Cyclopalladate complex of 3-benzyl-7-methyl-3,7-diazabicyclo[3.3.1]nonane

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Abstract

A new (C,N,N)-pincer cyclopalladate unsymmetrical complex of 3-benzyl-7-methyl-3,7-diazabicyclo[3.3.1]nonane (3-benzyl-7-methylbispidine) was synthesized and characterized. Catalytic performance of this complex was examined in the Heck and Suzuki reactions and in the norbornene hydroarylation.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    L. A. Bulygina, N. S. Khrushcheva, A. S. Peregudov & V. I. Sokolov

Authors
  1. L. A. Bulygina
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  2. N. S. Khrushcheva
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  3. A. S. Peregudov
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  4. V. I. Sokolov
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Corresponding author

Correspondence to L. A. Bulygina.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2479—2484, October, 2016.

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Bulygina, L.A., Khrushcheva, N.S., Peregudov, A.S. et al. Cyclopalladate complex of 3-benzyl-7-methyl-3,7-diazabicyclo[3.3.1]nonane. Russ Chem Bull 65, 2479–2484 (2016). https://doi.org/10.1007/s11172-016-1610-x

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  • DOI: https://doi.org/10.1007/s11172-016-1610-x

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