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Oxidative splitting of secondary cycloalkanols by Pb(OAc)4-LiCl AND Pb(OAc)4-Cu(OAc)2 systems

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

As the result of the reaction of cyclopentanol and cyclohexanol with the Pb(OAc)4-LiCl and Pb(OAc)4-Cu(OAc)2 systems, ω-formylalkyl radicals CH2(CH2)n+1CHO (n=2, 3) are formed, which are oxidized by these systems into ω-chloroalkanals and ω-alkenals, respectively.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    G. I. Nikishin & N. I. Kapustina

Authors
  1. G. I. Nikishin
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  2. N. I. Kapustina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1345–1348, June, 1984.

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Nikishin, G.I., Kapustina, N.I. Oxidative splitting of secondary cycloalkanols by Pb(OAc)4-LiCl AND Pb(OAc)4-Cu(OAc)2 systems. Russ Chem Bull 33, 1235–1239 (1984). https://doi.org/10.1007/BF00948994

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  • DOI: https://doi.org/10.1007/BF00948994

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