Skip to main content
SpringerLink
Log in

Complex formation between alkylpyridines and Na3PO4 under gas chromatography conditions

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The specific retention volumes, the differential molar free energies, enthalpies, and entropies of sorption for twelve pyridine bases have been determined by gas chromatography on columns containing equimolar amounts of the salts sodium orthophosphate and potassium fluoride, with hydrogenated Apiezon L as the stationary phase.

  2. 2.

    Alkylpyridines form donor-acceptor complexes with sodium orthophosphate and the thermodynamic characteristics of complex formation have been calculated.

  3. 3.

    A method is proposed for calculating the temperature limit of complex formation under chromatography conditions and the stability temperatures of the complexes have been determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. R. V. Golovnya, I. L. Zhuravleva, and B. M. Polanuer, Izv. Akad. Nauk SSSR, Ser. Khim., 2198 (1983).

  2. R. V. Golovnya and A. L. Samusenko, J. Chromatogr.,217, 183 (1981).

    Google Scholar 

  3. R. V. Golovnya, A. L. Samusenko, and E. A. Mistryukov, High Resol. Chromatogr. Chromatogr. Commun.,2, 6–9 (1979).

    Google Scholar 

  4. R. V. Golovnya, I. L. Zhuravleva, S. V. Zenin, V. A. Polyakov and G. B. Sergeev, Izv. Akad. Nauk SSSR, Ser. Khim., 2595 (1973).

  5. D. H. Desty and W. T. Swanton, J. Phys. Chem.,65, 766 (1961).

    Google Scholar 

  6. R. V. Golovnya and A. L. Samusenko, Izv. Akad. Nauk SSSR, Ser. Khim., 2060 (1981).

  7. E. T. Denisov, Kinetics of Homogeneous Chemical Reactions [in Russian], Vysshaya Shkola, Moscow (1978), p. 139.

    Google Scholar 

  8. L. P. Hammett, Physical Organic Chemistry, McGraw-Hill (1970).

  9. R. V. Golovnya and D. N. Grigor'eva, Izv. Akad, Nauk SSSR, Ser, Khim., 1400 (1983).

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    R. V. Golovnya, I. L. Zhuravleva & B. M. Polanuer

Authors
  1. R. V. Golovnya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. L. Zhuravleva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. B. M. Polanuer
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2487–2491, November, 1984.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Golovnya, R.V., Zhuravleva, I.L. & Polanuer, B.M. Complex formation between alkylpyridines and Na3PO4 under gas chromatography conditions. Russ Chem Bull 33, 2276–2280 (1984). https://doi.org/10.1007/BF00948837

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00948837

Keywords

Search

Navigation