Conclusions
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1.
In catalysts containing copper salts on aluminum oxide support, various structures containing copper have been found that form by the reaction of the salt with the support surface.
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2.
The kind of structure that forms depends on the phase composition and the acid-base properties of the support surface.
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3.
Surface structures can affect the coalescence of catalyst particles under reaction conditions, and thus change the hydrodynamics of a fluidized bed.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2431–2437, November, 1984.
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Solomonik, I.G., Kurlyandskaya, I.I., Yakerson, V.I. et al. Catalytic systems for oxidative chlorination of hydrocarbons Communication 3. Properties of catalysts containing copper salts on an aluminum oxide support. Russ Chem Bull 33, 2222–2226 (1984). https://doi.org/10.1007/BF00948825
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DOI: https://doi.org/10.1007/BF00948825