Skip to main content
SpringerLink
Log in

Isotope exchange of hydrogen and protonation of complexes η6-ArCr (CO)2 (η2-C4H2O3)

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study has been made of the reaction of hydrogen isotope exchange in CF3COOD byη 6-C6H6Cr(CO)2(η 2-C4H2O3),η 6-(CH3)3C6H3Cr(CO)2(η 3-C4H2O3), andη 6-C6H6Cr(CO)3, at 70°C. It has been found that the maleic anhydride does not have any great effect on the reactivity of theη 6-areae ligand in theη 6-C6H6Cr(CO)2 (η 2-C4H2O3) andη 6-(CH3)3C6H3Cr(CO)2(η 2-C4H2O3) in comparison with the CO ligand inη 6-C6H6Cr(CO)3

  2. 2.

    On the basis of IR spectra and1H and13C NMR spectra, it has been established that in acidic media, protonation takes place at the carbonyl groups of the maleic anhydride of the complexesη 6-ArCr(CO)2(η 2-C4H2O3).

  3. 3.

    A new complex,η 6-C6H5COOCH3Cr(CO)2 (η 2-C4H2O3), has been synthesized and characterized by its spectra.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. M. Herberhold and C. R. Jablonski, Inorg. Chim. Acta,7, 241 (1973).

    Google Scholar 

  2. Yu. T. Struchkov, V. G. Andrianov, V. N. Setkina, N. K. Baranetskaya, V. I. Losilkina, and D. N. Kursanov, J. Organomet. Chem.,182, 213 (1979).

    Google Scholar 

  3. V. N. Setkina, V. I. Zdanovich, N. K. Baranetskaya, A. I. Yurtanov, K. N. Anisimov, and D. N. Kursanov, Zh. Obshch. Khim.,41, 1338 (1971).

    Google Scholar 

  4. D. N. Kursanov, V. N. Setkina, P. V. Petrovskii, V. I. Zdanovich, N. K. Baranetskaya, and I. D. Rubin, J. Organomet. Chem.,37, 339 (1972).

    Google Scholar 

  5. G. Olah and S. H. Yu, J. Org. Chem.,41, 717 (1976).

    Google Scholar 

  6. B. V. Lokshin, V. I. Zdanovich, N. K. Baranetskaya, V. N. Setkina, and D. N. Kursanov, J. Organomet. Chem.,37, 331 (1972).

    Google Scholar 

  7. Yu. N. Sukharev and Yu. S. Nedrasov, Org. Mass Spectrom.,11, 1239 (1976).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. I. Losilkina, P. V. Petrovskii, N. K. Baranetskaya & V. N. Setkina

Authors
  1. V. I. Losilkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. P. V. Petrovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. K. Baranetskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. N. Setkina
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 787–791, April, 1984.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Losilkina, V.I., Petrovskii, P.V., Baranetskaya, N.K. et al. Isotope exchange of hydrogen and protonation of complexes η6-ArCr (CO)2 (η2-C4H2O3). Russ Chem Bull 33, 723–726 (1984). https://doi.org/10.1007/BF00947821

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00947821

Keywords

Search

Navigation