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Bromine- and iodine-containing (Haloalkyl)trichlorosilanes and methyl(Haloalkyl)chlorosilanes and their conversions

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The organosilicon monomers XCH2(CH3)3 3−nSiCln with X=Cl (n=2, 3) are smoothly converted when reacted with aluminum iodide or aluminum bromide into the corresponding C-iodo and C-bromo derivatives (X=I, Br). Compounds with the general formula X(CH2)m(CH3)3−n,SiCln with X=Cl are converted upon reaction with NaI into the corresponding C-iodo derivatives (X=I).

  2. 2.

    When reacted with SbF3 or KHF2, (iodoalkyl)- and (bromoalkyl)trichlorosilanes are converted into the corresponding (haloalkyl)trifluorosilanes.

  3. 3.

    The corresponding (iodoalkyl)- and (bromoalkyl)silatranes and their exo-D-methyl derivatives have been synthesized on the basis of the (haloalkyl)trichlorosilanes obtained.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    V. M. D'yakov, Yu. A. Lukina, M. G. Voronkov, L. I. Gubanova, G. A. Samsonova & S. N. Tandura

Authors
  1. V. M. D'yakov
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  2. Yu. A. Lukina
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  3. M. G. Voronkov
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  4. L. I. Gubanova
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  5. G. A. Samsonova
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  6. S. N. Tandura
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2366–2372, October, 1978.

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D'yakov, V.M., Lukina, Y.A., Voronkov, M.G. et al. Bromine- and iodine-containing (Haloalkyl)trichlorosilanes and methyl(Haloalkyl)chlorosilanes and their conversions. Russ Chem Bull 27, 2098–2104 (1978). https://doi.org/10.1007/BF00946535

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  • DOI: https://doi.org/10.1007/BF00946535

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