Conclusions
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1.
The sulfotrioxidation of hexafluorodimethylketenals by sulfuric anhydride begins with the attack of an ethereal oxygen, the direction of the reaction being determined by the nature of the alkoxyl group.
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2.
2-H-Hexafluoropropane-2-sulfonyl fluoride has been synthesized by reacting hexafluoro-isobutenylidene sulfate with 1,1-bis(β-chloroethoxy)hexafluoroisobutylene.
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A. F. Eleev, G. A. Sokol'skii, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 1383 (1975).
J. D. Roberts and M. C. Caserio, Basic Principles of Organic Chemistry, W. A. Benjamin, New York (1964).
A. F. Eleev, G. A. Sokol'skii, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 397 (1974).
V. M. Pavlov, V. N. Derkachev, G. A. Sokol'skii, and I. L. Knunyants, Khim. Geterotsikl. Soedin., 1321 (1973).
G. A. Sokol'skii, V. M. Pavlov, V. N. Golovkin, and I. L. Knunyants, Khim. Geterotsikl. Soedin., 472 (1974).
A. F. Eleev, G. A. Sokol'skii, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 1573 (1977).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2360–2366, October, 1978.
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Eleev, A.F., Sokol'skii, G.A. & Knunyants, I.L. Fluorine-containing β-sultones 48. Sulfotrioxidation of hexafluorodimethylketenals. Russ Chem Bull 27, 2093–2098 (1978). https://doi.org/10.1007/BF00946534
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DOI: https://doi.org/10.1007/BF00946534