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Diene systems in π-σ complexing with halogens

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study has been made of the formation of unstable π-σ complexes of cyclic and acyclic dienes with halogens at 77°K.

  2. 2.

    The tendency toward complex formation with the halogens is much the same in the cyclopentadienes and the monoolefins; the donor activity of the acyclic dienes is somewhat lower.

  3. 3.

    Only one double bond participates in diene complexing.

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Authors and Affiliations

  1. Institute of Spectroscopy, Academy of Sciences of the USSR, Moscow

    Ya. M. Kimel'fel'd, L. M. Mostovaya, S. A. Yankovskii & V. A. Mironov

  2. Moscow Institute of the Meat and Dairy Industry, USSR

    Ya. M. Kimel'fel'd, L. M. Mostovaya, S. A. Yankovskii & V. A. Mironov

Authors
  1. Ya. M. Kimel'fel'd
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  2. L. M. Mostovaya
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  3. S. A. Yankovskii
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  4. V. A. Mironov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2273–2276, October, 1978.

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Kimel'fel'd, Y.M., Mostovaya, L.M., Yankovskii, S.A. et al. Diene systems in π-σ complexing with halogens. Russ Chem Bull 27, 2010–2013 (1978). https://doi.org/10.1007/BF00946516

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  • DOI: https://doi.org/10.1007/BF00946516

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