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Hydrogen activation on silica gels containing transition-metal ions

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Silica gels containing Co2+ and Ni2+ ions will catalyze the H2-D2 exchange reaction after thermal treatment in vacuum, differing in this respect from similar V5+ ion systems.

  2. 2.

    The activation of H2 molecules in longitudinal (model I) and transverse (model T) configurations in the coordination spheres of Co2+, Ni2+, and V5+ ions has been treated through semiempirical MO LCAO calculations. This work has led to an interpretation of the experimental results and to a mechanism for the H2−D2 reaction through type-I complexes.

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Literature cited

  1. D. A. Dowden and D. Wells, Actes du 2-ème Congres Internationale de Catalyse, Technip, Paris (1961), p. 1499.

  2. A. D. Shuklov, S. A. Surin, B. N. Shelimov, and V. B. Kazanskii, Kinet. Katal.,16, 468 (1975).

    Google Scholar 

  3. A. D. Shuklov, B. N. Shelimov, and V. B. Kazanskii, Khim. Vys. Energ.,10, 145 (1976).

    Google Scholar 

  4. V. M. Vorotyntsev, V. A. Shvets, and V. B. Kazanskii, Kinet. Katal.,12, 678 (1971).

    Google Scholar 

  5. N. D. Chuvylkin and G. M. Zhidomirov, Zh. Strukt. Khim.,12, 347 (1971).

    Google Scholar 

  6. V. A. Kaverinskii, V. Yu. Borovkov, V. A. Shvets, and V. B. Kazanskii, Kinet. Katal.,15, 819 (1974).

    Google Scholar 

  7. I. D. Mikheikin, G. M. Zhidomirov, and V. B. Kazanskii, Zh. Fiz. Khim.,46, 534 (1972).

    Google Scholar 

  8. M. Zerner and C. Gouterman, Inorg. Chem.,5, 1699, 1707 (1966).

    Google Scholar 

  9. G. Burnes, J. Chem. Phys.,41, 1521 (1964).

    Google Scholar 

  10. R. S. Mulliken, J. Chem. Phys.,23, 1833 (1955).

    Google Scholar 

  11. A. I. Lumpov, I. D. Mikheikin, N. D. Chuvylkin, G. M. Zhidomirov, and V. B. Kazanskii, Kinet. Katal.,17, 802 (1976).

    Google Scholar 

  12. N. N. Bulgakov and Yu. A. Borisov, Kinet. Katal.,7, 1007 (1966).

    Google Scholar 

  13. T. Anno and Y. Sakai, J. Chem. Phys.,56, 922 (1972).

    Google Scholar 

  14. V. Yu. Borovkov, G. M. Zhidomirov, and V. B. Kazanskii, Kinet. Katal.,16, 1334 (1975).

    Google Scholar 

  15. N. D. Chuvylkin, G. M. Zhidomirov, and V. B. Kazanskii, Kinet. Katal.,16, 1334 (1975).

    Google Scholar 

  16. V. B. Kazanskii and N. D. Chuvylkin, Dokl. Akad. Nauk SSSR,223, 910 (1975).

    Google Scholar 

  17. B. M. Gimarc, J. Chem. Phys.,53, 1623 (1970).

    Google Scholar 

  18. L. J. Shaad and W. V. Hikes, J. Chem. Phys.,61, 1934 (1974).

    Google Scholar 

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. D. Shuklov, N. D. Chuvylkin, B. N. Shelimov & V. B. Kazanskii

Authors
  1. A. D. Shuklov
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  2. N. D. Chuvylkin
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  3. B. N. Shelimov
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  4. V. B. Kazanskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2239–2243, October, 1978.

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Shuklov, A.D., Chuvylkin, N.D., Shelimov, B.N. et al. Hydrogen activation on silica gels containing transition-metal ions. Russ Chem Bull 27, 1977–1981 (1978). https://doi.org/10.1007/BF00946509

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  • DOI: https://doi.org/10.1007/BF00946509

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