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Reaction of tetraalkylammonium octahydrotriborates with Al(BH4)3

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    When [R4N]B3H8 (R=CH3, C2H5, or C4H9) reacts with Al(BH4)3, the end solid products are complexes [R4N]Al(BH4)4.

  2. 2.

    The authors propose a scheme of the process, including formation of intermediate complexes [R4N][Al(BH4)3(B3H8)], unstable at room temperature, and their decomposition with evolution of B2H4, and formation of [R4N]Al (BH4)4].

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Authors and Affiliations

  1. Institute of New Chemical Problems, Academy of Sciences of the USSR, Chernogolovka

    L. V. Titov, E. R. Eremin, V. P. Nikol'skaya & V. Ya. Rosolovskii

Authors
  1. L. V. Titov
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  2. E. R. Eremin
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  3. V. P. Nikol'skaya
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  4. V. Ya. Rosolovskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2212–2215, October, 1978.

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Titov, L.V., Eremin, E.R., Nikol'skaya, V.P. et al. Reaction of tetraalkylammonium octahydrotriborates with Al(BH4)3 . Russ Chem Bull 27, 1953–1956 (1978). https://doi.org/10.1007/BF00946504

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  • DOI: https://doi.org/10.1007/BF00946504

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