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Ring-chain tautomerism of substituted hydrazones

II. Derivatives of 1-hydrazino- and 1-(N-Alkylhydrazino)-2-propanols

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

1-Hydrazino-2-propanol reacts with aliphatic carbonyl compounds to form the corresponding (2-hydroxypropyl)hydrazones. 1-(N-Alkylhydrazino)-2-propanols, on the other hand, give tautomeric mixtures of alkyl-substituted perhydro-1,3,4-oxadiazines and N-alkyl-N-(2-hydroxypropyl)hydrazones. As compared with derivatives of 2-(N-alkylhydrazino)ethanols, the position of the equilibrium in the investigated cases is shifted to favor the cyclic forms.

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See [1] for communication I.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 301–308, March, 1971.

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Potekhin, A.A., Zaitsev, B.D. Ring-chain tautomerism of substituted hydrazones. Chem Heterocycl Compd 7, 277–283 (1971). https://doi.org/10.1007/BF00944403

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  • DOI: https://doi.org/10.1007/BF00944403

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