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Transsilylation of disilazanes with 1-chloro-1-methyl-1-silacyclobutane and other triorganylchlorosilanes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The first stage of the reaction of hexamethyldisilazane with 1-chloro-1-methyl-1-silacyclotmtane gives 1,3,3,3-tetramethyl-1,1-trimethylenedisilazane

, and after that 1,3-dimethyl-1,3-bis(trimethylene)disilazane

is formed. The latter reacts with 1-chloro-1-methyl-1-silacyclobutane to give tris[methyl(trimethylene)silyl] amine

. From a large number of examples it is shown that transsilylation of disilazanes with chlorosilanes is a general reaction.

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References

  1. N. S. Nametkin, V. M. Vdovin, E. D. Babich, and V. D. Oppengeim, KhGS [Chemistry of Heterocyclic Compounds], 455, 1965.

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Authors and Affiliations

  1. Institute of Petrochemical Synthesis, AS USSR, Moscow

    N. S. Nametkin, V. M. Vdovin & E. D. Babich

Authors
  1. N. S. Nametkin
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  2. V. M. Vdovin
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  3. E. D. Babich
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Nametkin, N.S., Vdovin, V.M. & Babich, E.D. Transsilylation of disilazanes with 1-chloro-1-methyl-1-silacyclobutane and other triorganylchlorosilanes. Chem Heterocycl Compd 3, 105–108 (1967). https://doi.org/10.1007/BF00944277

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  • DOI: https://doi.org/10.1007/BF00944277

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