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Atranes

X. 1-Aroxytitatranes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A method is developed for synthesizing hitherto unknown 1-aroxytitatranes\(ArOTi(O---\begin{array}{*{20}c} | \\ C \\ | \\ \end{array} ---\begin{array}{*{20}c} | \\ C \\ | \\ \end{array} )_3 N\), where Ar is aryl, and the carbon atoms in the O-C-C-N groups are linked to hydrogen atoms or hydrocarbon substituents. It is based on transesterification of tetra-alkyltitanates with an equimolecular mixture of tri(β-hydroxyalkyl)amine and appropriate phenol (naphthol). 17 compounds of the given type were prepared and characterized by this means, the yields basically exceeding 90%.

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References

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Authors and Affiliations

  1. Institute of Organic Synthesis, AS LatvSSR, Riga

    M. G. Voronkov & D. F. Faitel'son

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  1. M. G. Voronkov
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  2. D. F. Faitel'son
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For Part XI see [1].

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Voronkov, M.G., Faitel'son, D.F. Atranes. Chem Heterocycl Compd 3, 28–30 (1967). https://doi.org/10.1007/BF00944251

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  • DOI: https://doi.org/10.1007/BF00944251

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